15.7 Phosphorus, yellow or white
Clasification Society 2024 - Version 9.40
Statutory Documents - IMO Publications and Documents - International Codes - IBC Code - International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in BulkAmended by Resolution MEPC.225(64) - Chapter 15 Special requirements - 15.7 Phosphorus, yellow or white

15.7 Phosphorus, yellow or white

  15.7.1 Phosphorus shall, at all times, be loaded, carried and discharged under a water pad of 760 mm minimum depth. During discharge operations, arrangements shall be made to ensure that water occupies the volume of phosphorus discharged. Any water discharged from a phosphorus tank shall be returned only to a shore installation.

  15.7.2 Tanks shall be designed and tested to a minimum equivalent water head of 2.4 m above the top of the tank, under designed loading conditions, taking into account the depth, relative density and method of loading and discharge of the phosphorus.

  15.7.3 Tanks shall be so designed as to minimize the interfacial area between the liquid phosphorus and its water pad.

  15.7.4 A minimum ullage space of 1% shall be maintained above the water pad. The ullage space shall be filled with inert gas or naturally ventilated by two cowled standpipes terminating at different heights but at least 6 m above the deck and at least 2 m above the pump-house top.

  15.7.5 All openings shall be at the top of cargo tanks, and fittings and joints attached thereto shall be of materials resistant to phosphorus pentoxide.

  15.7.6 Phosphorus shall be loaded at a temperature not exceeding 60°C.

  15.7.7 Tank heating arrangements shall be external to tanks and have a suitable method of temperature control to ensure that the temperature of the phosphorus does not exceed 60°C. A high-temperature alarm shall be fitted.

  15.7.8 A water drench system acceptable to the Administration shall be installed in all void spaces surrounding the tanks. The system shall operate automatically in the event of an escape of phosphorus.

  15.7.9 Void spaces referred to in 15.7.8 shall be provided with effective means of mechanical ventilation which shall be capable of being sealed off quickly in an emergency.

  15.7.10 Loading and discharge of phosphorus shall be governed by a central system on the ship which, in addition to incorporating high-level alarms, shall ensure that no overflow of tanks is possible and that such operations can be stopped quickly in an emergency from either ship or shore.

  15.7.11 During cargo transfer, a water hose on deck shall be connected to a water supply and kept flowing throughout the operation so that any spillage of phosphorus may be washed down with water immediately.

  15.7.12 Ship-to-shore loading and discharge connections shall be of a type approved by the Administration.


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