Section 11 High strength steel for special marine applications
Clasification Society 2024 - Version 9.40
Clasifications Register Rules and Regulations - Rules for the Manufacture, Testing and Certification of Materials, July 2022 - Chapter 3 Rolled Steel Plates, Strip, Sections and Bars - Section 11 High strength steel for special marine applications

Section 11 High strength steel for special marine applications

11.1 Goal-based framework

11.1.1 The purpose of this Section is to present a goal-based approach to the requirements for high strength steel for special marine applications, not covered elsewhere in the Rules for the Manufacture, Testing and Certification of Materials, July 2022. Whilst the primary intent of the application of the material listed herein is for pressure vessels/submersible craft intended for human occupancy, use and application of this material for other constructions may be specially considered within the scope of the goal-based framework.

11.1.2 The goals, functional requirements and performance requirements listed herein relate to the manufacture and testing of applicable base materials.

11.1.3 In addition to this goal-based framework, the relevant requirements of the Rules for the Manufacture, Testing and Certification of Materials, July 2022 are to be complied with to achieve certification. In order to satisfy the goal-based framework in this Chapter, it is also necessary to comply with the applicable Rules related to materials, manufacture, testing, survey and classification.

11.1.4 The list of goals is as follows:

  1. The material shall withstand the applied design loads and integrity requirements for minimising the risk of loss of the structure due to failure.
  2. The material for components, products and systems shall minimise the hazard to persons, assets or environment in any foreseeable operating conditions.

11.1.5 The list of functional requirements (FR) is as follows:

  1. The material shall be manufactured and finished so as to provide assurance that the appropriate quality and mechanical property requirements are achieved.
  2. The material shall be weldable.
  3. The material shall function in a safe and acceptable manner, for compliance with manufacturing and design criteria.

11.1.6 The list of performance requirements (PR) is as follows:

  1. The material shall have the mechanical properties, for Material Class (Special Application), as specified in Table 3.11.1 Essential mechanical properties for Material Class Special Applications 1 and 2, and any other project requirements.
  2. The material shall have the chemical composition for the appropriate Material Class (Special Application 1 or 2), as specified in Table 3.11.2 Chemical composition for Material Class Special Applications 1 and 2, and any other project requirements.
  3. The material shall demonstrate the ability to:
    1. Withstand explosive loading, when applicable.
    2. Meet suitable toughness requirements as required by the application and by the specified testing regime.
    3. Withstand tensile loads under the specified operating conditions and meet the requirements of a specified testing regime.
    4. Be suitably ductile for loads under the specified operating conditions and meet the requirements of a specified testing regime.
  4. Meet specified identification, dimensional and quality requirements.
  5. All material shall be in the quenched and tempered supply condition or be subject to alternative rolling and heat treatment parameters according to the approved manufacturing specification in order to achieve the required mechanical properties.
  6. The weldability of the material shall be confirmed by either an evidence-based regime according to a recognised method, or by a performance-based regime, agreed with LR:
    1. The maximum carbon equivalent value (CEV), when calculated using UK Defence Standards criteria, shall be as specified in Table 3.11.3, Carbon equivalent values for Material Class Special Applications 1 and 2.).
    2. The maximum CEV values, when calculated using LR Rules, shall be as per the values of H55QT or H69QT (for Material Class Special Applications 1 and 2 respectively), within Table 3.10.3 Maximum Ceq, CET and Pcm values.
  7. A typical tensile strength value will be in the range of 640-820 N/mm2, for Material Class Special Application 1.
  8. A typical tensile strength value will be in the range of 725-860 N/mm2, for Material Class Special Application 2.

Table 3.11.1 Essential mechanical properties for Material Class Special Applications 1 and 2

Material Class (Special Application) (see Note 1) Yield strength (or 0,2% proof strength) (minimum) N/mm2 Elongation (minimum) % Charpy value J (minimum) Charpy test temperature °C Hardness value (HB)
High Strength Steel – Special Application 1 550 20 80 −80 207 - 248
High Strength Steel – Special Application 2 690 18 80 −80  
      For thickness >60mm   228 - 270
      70 −80  
Note 1. In addition to the above performance requirements for essential mechanical properties (for Material Class Special Applications 1 and 2), the following tables provide further details for tensile, hardness, and Charpy impact requirements, should the LR accepted solution route be followed.

Table 3.11.2 Chemical composition for Material Class Special Applications 1 and 2

Material Class (Special Application)

Material grade chemical composition High Strength Steel – Special Application 1 High Strength Steel – Special Application 2
Element (%) by weight
All thickness ranges

(see Note 1)

Plate Thickness (mm)
6 to 32 inclusive

(see Note 5)

Over 32 to 76

(see Note 5)

Over 76 to 140

(see Note 5)

Carbon ≤0,18 0,10 – 0,18 0,14 – 0,20 0,14 – 0,20
Manganese 0,10–0,40 0,10 – 0,40 0,10 – 0,40 0,10 – 0,40
Aluminium (see Note 2) 0,015–0,060 0,015 – 0,060 0,015 – 0,060 0,015 – 0,060
Phosphorus (see Note 3) ≤0,015 0,015 0,015 0,015
Sulphur ≤0,008 0,004 0,004 0,004
Silicon 0,15–0,35 0,15 – 0,38 0,15 – 0,38 0,15 – 0,38
Nickel 2,25–3,25 2,25 – 3,50 2,75 – 3,50 3,00 – 3,50
Chromium 1,00–1,80 1,00 – 1,80 1,40 – 1,80 1,50 – 1,90
Molybdenum 0,2–0,6 0,20 – 0,60 0,35 – 0,60 0,50 – 0,65
Nitrogen (see Note 2) ≤0,012 0,010 0,010 0,010
Residual elements        
Titanium ≤0,020 0,02 0,02 0,02
Vanadium ≤0,020 0,03 0,03 0,03
Copper ≤0,20 0,25 0,25 0,25
Arsenic ≤0,03 0,025 0,025 0,025
Antimony ≤0,010 0,025 0,025 0,025
Lead ≤0,005 Not specified Not specified Not specified
Tin ≤0,02 0,030 0,030 0,030
Cobalt (see Note 4) ≤0,03 0,030 0,030 0,030
Note 1. The listed product percentage by weight values also apply to ladle percentage weight values, with the exception of sulphur, where the maximum percentage weight value is ≤0,006.
Note 2. The steel is to be fully killed, using aluminium fine grain practice, with a minimum aluminium content of 0,015 per cent and greater than twice the percentage nitrogen.
Note 3. Where plates are specified as subject to stress relief, the preferred maximum phosphorus content is 0,010 per cent and is not to exceed 0,012 per cent.
Note 4. For Naval submersible craft with nuclear propulsion, and where the project authority requires, each castis to be analysed for cobalt. Where the content exceeds 0,030 per cent, instructions are to be obtained from the project authority before release of the product. For commercial submersible craft, there is no requirement for cobalt content analysis.
Note 5. Single values are maximum percentages. These elements should not be added deliberately.

11.2 LR accepted solutions for high strength steel for special marine applications

11.2.1 Provision is made in this Section for weldable high strength steels intended for use in special marine applications, which are not covered elsewhere in this Chapter.

11.2.2 An accepted solution for satisfactorily meeting the goal-based framework is specified in sub-Sections Ch 3, 11.3 General requirements to Ch 3, 11.12 Visual and NDE requirements of this Section.

11.2.3 The application, in entirety, of the prescriptive content in this Section (including any references leading out) is considered to meet the listed goals.

11.2.4 Alternative proposals for meeting the goal-based framework in Ch 3, 11.1 Goal-based framework will be specially considered.

11.2.5 The requirements presented herein represent an accepted material solution to meet the requirements of High Strength Steel – Special Application 1 and Special Application 2, of which Q1(N) and HY100 (UK) grades of rolled plate are respective examples.

11.3 General requirements

11.3.1 In addition to the requirements of this sub-Section, fulfilment of an accepted solution also requires compliance with the relevant Sections of the Rules for the Manufacture, Testing and Certification of Materials, July 2022, specifically;

regarding approval and manufacture, testing, inspection and general requirements for materials.

11.3.2  Supplied High Strength Steel – Special Application 1plate product is to be in the thickness range 6,00 mm to 150 mm.

11.3.3 Supplied High Strength Steel – Special Application 2 plate product is to be in the thickness range 6,00 mm to 140 mm.

11.4 Manufacture and chemical composition

11.4.1 All plate products are to be produced by LR approved steelmaking processes, and any specific requirements for casting type shall be specified by the project.

11.4.2 High Strength Steel – Special Applications has strict chemical composition ranges and limits for feedstock (‘ladle’) and rolled product. These are indicated in Table 3.11.2 Chemical composition for Material Class Special Applications 1 and 2. Each cast is to be analysed using ladle samples. For product analysis, test samples are to be taken from mid-thickness at the top centre portion of each plate, as shown in Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

11.4.3 Carbon equivalent is to be calculated using the following formula, and the results compliant with the values listed in Table 3.11.3 Carbon equivalent values for Material Class Special Applications 1 and 2:
Note This CEV formula is only to be used for High Strength Steel – Special Application class steels. Other references to CEV formulae within LR Rules are not applicable to High Strength Steel – Special Application class steels. Similarly, this formula shall not be used to determine CEV for any other steel or product contained in other Rules, Chapters or Sections not related specifically to High Strength Steel – Special Application 1 or Special Application 2 class steel.

Table 3.11.3 Carbon equivalent values for Material Class Special Applications 1 and 2

High Strength Steel – Special Application 1 High Strength Steel – Special Application 2
Plate thickness (mm) Carbon equivalent values Plate thickness (mm) Carbon equivalent values
Target Maximum
6 – 30 mm 0,62 0,64 All thickness ranges 0,75 max
30,1 – 150 mm 0,66 0,70

11.5 Heat treatment

11.5.1 Plates are to be supplied in the quenched and tempered condition with the following specific requirements:
  1. (a) For Special Application 1, the plates shall be hardened by heating above the upper critical temperature, but not to more than 950°C, followed by water spray quenching. Subsequent quenching shall be in the range 600°C to 675°C. Heat treatment records are to be supplied for each batch. Pickling or flame descaling is not permitted after heat treatment.
  2. For Special Application 2, the manufacturer may determine the detailed procedure to produce plates meeting the mechanical property requirements with the exception that the final tempering temperature is to be in the range 660°C to 680°C. Plates, after receiving tempering and heat treatment, shall be cooled at a rate equal to or faster than air cooling.

11.5.2 Heat treatment, quenching and tempering operations are to be undertaken under controlled conditions. Furnaces are to be thermally monitored (including temperature uniformity) and calibrated to an appropriate International Standard.

11.6 Cleanliness

11.6.1 Plates are to be subject to inclusion content assessment in accordance with ASTM E45 (latest edition) requirements, as outlined in Table 3.11.4 Cleanliness requirements.

Table 3.11.4 Cleanliness requirements

Worst field (as per ASTM E45) Total fields see Notes 1 and 2
Type see Note 3 Severity level see Note 3

B + C + D ≤ 25
B, C, D (according to JK inclusion rating) ≤ 2
Note 1. The presence of any silicate material is not acceptable.
Note 2. Equivalent inclusion types to ASTM E45 may be used, as defined in standard EN 10247 (i.e. EB, EC, ED)
Note 3. Nomenclature relates to inclusion type and severity. Inclusion type and severity level terminology as stated in ASTM E45 (latest edition).

11.6.2 Material is to exhibit homogeneous microstructure throughout the section thickness and be free from macro segregation.

11.7 Dimensions, flatness, thickness and weight control

11.7.1 Plates are to be supplied to nominal dimensions as required in Table 3.11.5 Dimensional tolerances for Material Class Special Applications 1 and 2.

Table 3.11.5 Dimensional tolerances for Material Class Special Applications 1 and 2

Tolerance on length and width of plate for Special application 1
Length of plate Tolerance
Minus Plus
Up to and including 3000 mm 0 13 mm
Over 3000 mm up to and including 6000 mm 0 25 mm
Over 6000 mm 0 32 mm
Tolerance on length and width of plate for Special application 2
Thickness of plate Tolerance
Minus Plus
Up to and including 51 mm 6 mm 19 mm
Over 51 mm thick up to and including 102 mm 6 mm 25 mm
Over 102 mm 6 mm 29 mm

11.7.2 Plates are to comply with the flatness tolerances in Table 3.11.6 Flatness tolerance for plate and measurement information for Special Application 1 and Table 3.11.7 Flatness tolerance for plate and measurement information for Special Application 2.

Table 3.11.6 Flatness tolerance for plate and measurement information for Special Application 1

Thickness Flatness tolerance
Less than or equal to 12 mm 10 mm/metre
Greater than 12 mm but less than or equal to 150 mm 6 mm/metre
Method of measurement (a) If the pitch of waviness is less than 1 m, the measurement should be made by a 1 m straight edge across affected edges.

(b) If the pitch of waviness is greater than 1 m, the measurement should be made by a 2 m straight edge across the affected edges.

Table 3.11.7 Flatness tolerance for plate and measurement information for Special Application 2

Thickness (mm) Flatness Tolerances for specified widths (mm) (see Notes 1, 2 and 3)

Up to

900

900 to 1,200 1,200 to 1,500 1,500 to 1,800 1,800 to 2,100 2,100 to 2,400 2,400 to 2,700 2,700 to 3,000 3,000 to 3,600 Over 3,600
6 to 10 19 24 29 35 44 48 51 57 60 -
Over 10 up to 13 19 22 24 24 29 33 38 41 48 70
Over 13 up to 19 16 19 22 22 25 29 32 35 41 57
Over 19 up to 25 16 19 22 22 24 25 29 33 38 51
Over 25 up to 51 14 16 19 21 22 24 25 25 25 41
Over 51 up to 102 13 14 18 19 19 19 19 22 25 32
Over 102 up to 140 14 18 19 19 22 22 24 29 32 32
Measurement The flatness as specified in the table is to be an overall flatness factor. This factor is not to apply to 'kinks' or 'waviness'. The waviness or kinking permitted is to be evaluated by laying a one metre straight edge across the affected edges. The maximum permissible deviation from the straight edge is 6,5 mm.
Note 1. Flatness tolerances for length and width. The longer dimension specified is considered the length and variations from a flat surface along the length are not to exceed the tabular amount for the specified width in any 4,0 metres of length.
Note 2. When the longer dimension is under 1 metre, the variation in flatness is not to exceed 6 mm.
Note 3. The above table and notes cover the flatness tolerances of circular and sketch plates, based on the maximum dimensions of those plates.

11.7.3 All plates shall be subject to thickness gauging and weight control. Conformance criteria are shown in Table 3.11.8 Tolerances for thickness and weight control for Special Application 1 and Table 3.11.9 Tolerances for thickness and weight control for Special Application 2.

11.7.4 Thickness gauging may be taken by the use of calibrated mechanical or ultrasonic instruments, with the following grid sections to be applied:

  1. For undressed plates, grid lines are to be marked 25 mm from each edge and end, thereafter at intervals of 600 mm x 600 mm grid squares.
  2. For dressed areas, the grid size is reduced to 150 mm x 150 mm for plates up to and including 12 mm thick, and 300 mm x 300 mm for plates over 12 mm thick.

Table 3.11.8 Tolerances for thickness and weight control for Special Application 1

Item Plate thickness (mm) Tolerances
Thickness Maximum weight
Bulk orders

Small

orders or individual plates
Individual plates Batch
A 6,1–12 +2% −7% +2% +0 +2%
B 12,1–25 +1% −3% +1% +0 +1%
C 25,1 and over +1% −3% +1% +0 0
D Plates for insert pads +5% -0 Not applicable Not applicable Not applicable
Note 1. Where required by the project requirements, plates are to be weighed after final heat treatment with any surface dressing and abrasive blasting completed. Scale accuracy should be ±1,0 per cent of the nominal weight of subject plate.

Table 3.11.9 Tolerances for thickness and weight control for Special Application 2

Item Nominal Plate Thickness (mm) Thickness Tolerance
A 6 to 25 inclusive +0,75 mm - 0,25 mm
B Over 25,1 up to and including 75 +3% - 0,25 mm
C Over 75 +2,25 mm - 0,25 mm
Note 1. Where required by the project requirements, plates are to be weighed after final heat treatment with any necessary dressing of the surface and abrasive blasting completed. The machine accuracy should be ±1,0 per cent of the nominal weight of subject plate.

11.7.5 Weld repairs of plate defects are not permitted for either Special Application 1 or Special Application 2.

11.8 Surface preparation and priming

11.8.1 All plates shall be abrasively blasted in accordance with specific project requirements.

11.8.2 To avoid flash rusting and surface contamination following abrasive blasting, the steel shall be immediately coated with a prefabrication primer in accordance with the recommendations of the coating manufacturer.

11.8.3 Prefabrication primers shall be of a type specified by the project and approved by LR.

11.9 Mechanical tests

11.9.1 Sampling: Test specimens are to be taken from each finally heat-treated plate in accordance with Table 3.11.10 Mechanical test samples. The locations of test samples for mechanical testing, chemical analysis and metallography are indicated in Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

11.9.2 When required for Special Application 1, through thickness tensile requirements (sampling, testing and acceptance criteria) are to be defined by the project requirements which should, as a minimum, conform to EN 10164, and quality class Z35. For Special Application 2 through thickness tensile requirements are to be in accordance with Table 3.11.10 Mechanical test samples.

Table 3.11.10 Mechanical test samples

Dimensions Samples required
Plates over 3000 mm in length Tensile – as per Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

Charpy – as per Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

Samples acquired from both plate ends.

Hardness – test at diagonally opposite corners.

Through thickness tensile (where required) - as per Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

Plates under 3000 mm in length Tensile – as per Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

Charpy – as per Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

Samples acquired from one plate end only.

Hardness – test at diagonally opposite corners.

Through thickness tensile (where required) - as per Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography.

Notes: Through thickness tensile
  1. For all plate material equal or greater than 30 mm thick, full thickness short transverse tensile tests are to be taken from the first plate of the cast (top end) to assess through thickness ductility (according to EN 10164).
  2. Samples are to be taken from the positions shown in Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography. For non-extension pieces these are to be as per EN 10164:

    The test piece shall have the following diameter, do:

    do = 6 mm or 10 mm for 20 ≤ t ≤ 40, where t is the plate thickness in mm;

    do = 10 mm for 40 < t ≤ 400, where t is the plate thickness in mm.

  3. The acceptance criteria are to Quality Class Z35, as per EN 10164.
Notes: Tensile
  1. Tensile test specimens are to be in accordance with ISO 6892-1: Metallic materials – Tensile testing – Part 1: Method of test at room temperature.
  2. Test specimens circular in section of 200 mm2 cross-sectional area are to be taken from the quarter thickness position (providing that plate thickness is sufficient).
  3. For plates where 200 mm2 cross-sectional area test pieces can be taken, but not at quarter thickness position, the axis of the test piece is to be as close as possible to the quarter thickness position.
  4. For plates which are too thin for 200 mm2 cross- sectional area test pieces to be taken, the test pieces are to be the largest possible in accordance with ISO 6892-1.
  5. Rectangular section test pieces are to have a gauge length equal to 5,65√S0 where S0 is the cross-sectional area of the test piece.
Notes: Charpy
  1. Charpy: Middle line of test specimens is to coincide with mid-plate thickness.
  2. Charpy notch to be perpendicular to rolled surface.
  3. Charpy specimens to be machined at least 1,0 mm from surface.
  4. Standard 10 mm x 10 mm specimens. Sub size specimens permitted for material less than 12 mm thickness (i.e. 10 mm x 5 mm, 10 mm x 7,5 mm).
Notes: Hardness
  1. Test method ISO 6506-1: Metallic Materials- Brinell hardness test – Part 1: test method shall be used.
  2. If hardness results are outside of specification, batch to be investigated.

Figure 3.11.1 Location of test pieces for mechanical testing, chemical analysis and metallography

11.9.3 The results of mechanical tests shall comply with the appropriate requirements given in the following tables:

Table 3.11.11 Tensile and hardness properties for High Strength Steel for Material Class Special Applications 1 and 2

Material Class Thickness 0,2% Proof strength (N/mm2)

(see Notes 1 and 2)

Elongation % Reduction in area

%

Hardness

HB

Min Max Min Min Range
Special Application 1 ≤16 mm 550 690 20 - 207– 248
16,1 mm up to 150 mm 550 655 20 55 – Longitudinal

50 – Transverse

207–248
Special Application 2 <19 mm 690 825 18 - 228– 270

(Note 3)

19 mm up to 140 mm 690 825 18 45 – Transverse 228–270

(see Note 3)

Note 1. For High Strength Steel Special Application 1, the tensile strength is to be recorded and is to be such that the ratio of 0,2% proof strength to tensile strength for all plate thickness is not to exceed 0,90.
Note 2. For High Strength Steel Special Application 2, the tensile strength is to be recorded and is to be such that the ratio of 0,2% proof strength to tensile strength for plate thickness from 6 mm to less than 19 mm thick is not to exceed 0,95, and for plate thickness 19 mm and above, the ratio is not to exceed 0,92.
Note 3. If any result is outside the range 228 HB to 270 HB, the cause of the discrepancy between hardness and the normally expected tensile strength shall be fully investigated by the steel mill before the plate can be despatched from the steel mill. The project authority and LR shall be notified of the reasons for any discrepancy between the hardness and expected tensile results and any ensuing mitigation actions.

Table 3.11.12 Charpy impact properties for High Strength Steel for Material Class Special Applications 1 and 2

Material Class Thickness Charpy value

J

Charpy test temperature

°C

Special Application 1 <12 mm 80 (−80)
 

  65 (−80)
  for a 7,5 x 10 mm sample  
 

  or (−80)
 

  55  
  (5 mm x 10 mm sample)  
 

≥12 mm (see Note 1) 80 (−80)
Special Application 2 <12 mm 65 (−80)
  for a 7,5 x 10 mm sample, or;  
  5 mm x 10 mm sample  
 

 
12 mm up to 60 mm (see Note 2) 55 (−80)
  for a 10 x 10 mm sample  
 

 
>60 mm up to 140 mm (see Note 3) 70 (−80)
  for a 10 x 10 mm sample  
Note 1. The energy absorbed by each of the three test pieces (using a 10 x 10 mm sample) is to be greater than 80 Joules
Note 2. The average energy absorption of the three test pieces (using a 10 x 10 mm sample) for thicknesses up to 60 mm inclusive at each end of the plate is to be not less than 80 joules, and no single specimen is to be less than 70 joules.
Note 3. For plates over 60 mm thick the average value is to be not less than 70 joules, and no single value is to be less than 55 joules.

11.10 Identification of materials

11.10.1 Identification requirements are as follows:

  • All plates are to have unique identification to enable full traceability.
  • Plates are to be identified according to any project-specific requirements in addition to LR identification requirements.

11.11 Additional approval testing

11.11.1 The project requirements may specify appropriate and additional specialised testing for manufacturer approval.

11.11.2 The project specification will state the specific dynamic toughness testing procedure, or explosion testing, as applicable.

11.11.3 The project specification will state any additional tests for manufacturer approval, and the performance criteria and properties required.

11.12 Visual and NDE requirements

11.12.1 Visual and non-destructive examination (NDE): Surface inspection and verification of dimensions are the responsibility of the steelmaker and shall be carried out on all material prior to dispatch.

11.12.2 Surface discontinuities: After final heat treatment and abrasive blasting, e.g. shot blasting, each plate is to be examined visually for surface defects. Any surface discontinuities shall be defined as imperfections or defects, and are to comply with project specific acceptance criteria.

11.12.3 Internal defects: Examination for internal defects shall be carried out as required by the project specification and comply with project-specific acceptance criteria. Where project requirements for examination of plates are not specified, LR requires ultrasonic testing to be carried out, and the extent and acceptance criteria shall be agreed with LR.


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